Coperion

Degassing Processes in Twin Screw Compounders and Extruders

Highly efficient devolatilization technology in Coperion's twin screw extruders ensures the reliable removal of volatile organic compounds (VOCs), enhancing sensory quality of the product.

 

Depending on the process small (< 0.2 %) to large amounts (ca. 50 %) of volatiles have to be removed from the polymer melt rsp. solution or the solid polymer pellet. Required residual volatile levels depend on the type and the application of polymer.

Volatiles could be monomers, moisture, gases e.g. air or solvents. The type of volatile depends on the polymer and the way of polimerization.

As a provider of extrusion and compounding technology, Coperion offers comprehensive, tailor-made devolatilization solutions for compounding and extrusion processes. These range from the degassing of plastic melts and rubber to the production of practically odorless plastics compounds for packing materials or auto interiors.

Regardless of whether volatile components are available in small or large batch sizes, with a high or low boiling point – with our years of experience from numerous projects, tests, simulations and scale-ups, our specialists adapt every ZSK and STS twin screw extruder and compounder optimally to your  application.

Advantages of degassing in ZSK and STS twin screw extruders

↗ Intensive mixing behaviour – better distribution and release of trapped gas
↗ Frequent surface renewal – more melt surface area for gas escape
↗ Highly efficient vacuum devolatilization technology
↗ Incorporation of liquid stripping agents possible to intensify degassing
↗ Addition of water as stripping agent lowers the VOC by another 20–35%

 

Degassing principle of the ZSK twin screw extruder and
removal of VOCs within the extrusion processes

Degassing Principle in the ZSK Twin Screw Extruder

Reduction of VOCs in the twin screw extruder

ZSK and STS twin screw compounders form an excellent concept for devolatilization whether low or high amounts of volatiles, volatiles with low or high boiling point, have to be removed. 

For the processing of low-viscous, thin-bodied melts and for extrusion processes with high gas quantities we integrate our ZS-EG twin screw side degassing unit into compounding plants. With its large cross section for the devolatilization, it keeps the melt in the process section without product escape even at maximum specific torque of the extruder. Fumes or gases are reliably drawn off through the axially open screw flights. Increases in the throughput rate of up to 30 % with improved product quality are possible.

Calculations and trials in the Coperion test centers form the basis for the transfer and scale-up to production scale. 

Devolatilization of volatile ingredients from polymer melts

Polymer Type Parts before devolatilization Final content; extruder devolatilization
LDPE Ethylene < 3,000 ppm < 1,000 ppm
LLDPE Hexane, Cyclohexane 10-15% < 500 ppm
    3% < 250 ppm
EPDM Hexane, Cyclohexane 10-15% < 1,000 ppm
POE, PP Hexane, Cyclohexane 5-15% < 1,000 ppm
EVA Vinylacetate 5,000 ppm < 50 ppm
PS Styrene 3,000-5,000 ppm < 300 ppm
ABS Acrylonitrile (AN) 20 ppm < 4 ppm
PC Methylenchloride 20% < 50 ppm
PA 6 Caprolactame < 8% < 0.8%
SBR, SBS Hexane, Cyclohexane 15-70% < 1,000 ppm
Acrylic adhesive Acetone 50% < 1,000 ppm
Polyimid Chlorobenzene 70% < 500 ppm
PP various approx. 1,000 ppm < 50 ppm
PMMA MMA 10-40 % < 0.3%
POM H2O 5% < 100 ppm

 

Typical set-up for devolatilization of SBR or LLDPE

Multiple applications for degassing in plastics production

  • Plastics recycling
  • Devolatilization of SBR or LLDPE
  • Devolatilization of polycarbonate
  • Devolatilization of LDPE
  • Stabilizing and devolatilization of polyoxymethylen
  • Alloying and blending in one step

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